Analysis on the calculation methods of acid dew point of flue. The most important is the acid dew point which has an impact on the life of the process equipment. Later experimental work34 using a so 3 condenser method. Flue gas dew point temperature is the temperature where condensation of water vapor in the flue gas starts. Combatting hcl aciddewpoint corrosion at the geysers. Monitor and reduce acid smut emissions where acid smut is emitted into the atmosphere and lands on metal surfaces, it. Low temperature corrosion in boiler and its prevention. It will give you the sulfurous acid and sulfuric acid gas dew points. Temperature high enough above water dewpoint to avoid water condensation in coil.
Calculationplease do not change the formulae flue gas pressureair preheater outlet ppm vv fd fan outlet air temperture deg. Acid corrosion adt measurement point 1 3 2 01 32 1% 2. Decreasing the temperature of flue gas in boilers is one of the most effective ways to improve thermal efficiency, enhance electrostatic precipitator efficiency, and decrease water consumption of the desulfurization tower. Know what your hygrometer is reporting pressure dp or atm dp. Fuels used in boilers contain different levels of sulphur which is the primary cause for cold end corrosion. Dew point calculation 1 introduction the dew point temperature can easily be calculated from the relative humidity and temperature. For it to work, a smooth, shiny surface, like a mirror, is cooled until water vapor. Calculate the no2 dew point temperature of your flue gas. The flue gases combine with the moisture content in the air and form a specific dew point. Site reading so2 in flue gas vol % results s dew point temperature deg.
The theory explains how fog formation in the gas reduces the rate of acid deposition with a certain band of temperature between the acid dewpoint and the water dewpoint. Mar 18, 2014 dew point measurements for the wellstudied case of pure co2water agreed well with previous theoretical and experimental data over the range of pressure up to. A new correlation accurately predicts the fluegas sulfuricacid dewpoints to mitigate corrosion problems in process equipments and heatrecovery systems. Acid dew point calculation is based on the following. By reference to the table, the dew point is seen to be somewhere between 60 and 61 deg c 140141. Prediction of acid dew point in flue gas of boilers burning. Boiler is subcritical a reheat forced circulation drum boiler, the single chamber nshaped open layout and. Analysis on the calculation methods of acid dew point of. The traditional acid dew point of a gas is the temperature, at a given pressure, at which sulfuric acid in the gas phase will condense. To use, just enter a number in either one of the two dewpoint values, selecting appropriate units, or one of the four absolute values before pressing the calculate button. Benefits of sulphuric acid dewpoint temperature monitoring. When the vapor pressure is known, the dewpoint temperature can be found approximately from tables of svp, or more exactly by inverting a formula such as eq.
The dew point or dew point temperature of a gas is the temperature at which the water vapor or lowboiling hydrocarbon derivatives contained in the gas is transformed into the liquid state. The acid dew point also acid dewpoint of a flue gas i. For 20 percent water, a vapor pressure of 152 mmhg would be indicated. Jan 18, 2017 for instance, if a fuel that is sulfur free is combusted with around 30% excess air, moisture starts to condense out at a temperature of 1f 45c. Acid dew point calculation spreadsheet gases materials science. Calculation please do not change the formulae flue gas pressureair preheater outlet ppm vv fd fan outlet air temperture deg. An interpolation is performed, depending on water concentration in the flue gas.
The srk calculated dew point given in rr196 agrees slightly better with the manual droplet dew point than does the ametek automated dew point which was tuned to the iridescent ring. Get acid dew point of flue gas journal article osti. Sometimes, the acid gas dew points of the combustion product gases may be much higher than the dew point of water vapor alone without acid gases. Acid dew point calculation spreadsheet free download as excel spreadsheet. An improved thermodynamic correlation formula between the acid dew point and its influencing factors is also derived based on previous. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature or gas temperature is below of the acid dew point. It provides you also the h2so4 sulphuric acid concentration of the first liquid. If you find this website valuable and appreciate it is open and free for everybody please contribute by. The direct measurement of the process dew point provides plant and process operations with information that would otherwise be a multivariable equilibrium problem that is neither elementary, nor precise. The current calculation method of the acid dewpoint temperature of the flue gas is. Determination of dew point conditions for co2 with impurities. Acid dew point refining, hydrocarbons, oil, and gas.
Dew point calculator protected without password modified raoults law, one term margules gert a x1x2 system acetone1methanol2, b 0. Flue gas dew point corrosion occurs when these aggressive acids condense on carbon and stainless steels in convection sections, flue ducts, and stacks. Sten 1 has effective resistance to both sulfuric acid dew point corrosion and hydrochloric acid dew point corrosion, while sten 2 is effectively resistant to sulfuric acid dew point corrosion. Program can be expanded to include the hydrobromic, hydrochloric and nitric acid gas dew points if required. If a fuel with sulfur is burned under similar conditions along with water dew. These methods fall in the category of in combustion reduction and post combustion reduction. Acid dew point temperature for 5 typical acid gases back to full computer program list thermal efficiency of combustion systems is increased with the reduction in the exit flue gas temperature, however to low of an exit temperature could result in the condensation of acid gases that could corrode metallic surfaces in contact with those acids. Hydrocarbon dew point application emerson electric. Cases of acid dew point and flow a maharatna company. This calculator for flue gas carrying sox provides you a quick estimate of your flue gas acid dew point temperature. New correlation predicts flue gas sulfuric acid dewpoints.
At present, there are lots of calculation methods of acid dew point of flue gas. Flue gas heat recovery through the acid dew point heatmatrix group. Flue gas dewpoint fired process solutions steam reformer. Unlike traditional acid dew point meters, the absensoradm measures the dew point of combustion and process gases, independent of the condensable species i. The severity depends on many factors like percentage of sulphur in fuel, excess air, moisture in flue gas etc. I have come across two equations for sulfuric acid dew point calculation in flue gas. Pdf estimation of combustion flue gas acid dew point. When air cools to its dew point through contact with a surface that is colder than the air, water will condense on the surface. Determination of dew point conditions for co2 with. Dew point temperature of flue gases pdf sorry to see that you are blocking ads on the engineering toolbox. A poor guess can cause an interative calculation to diverge, giving a error, and the best way to recover is to reload the saved spreadsheet. When the calculated no2 dewpoint temperature is lower than the water dew point a straight water dew point line is.
Dew point is the temperature at which condensation will form. Prediction of acid dew point in flue gas of boilers burning fossil. Experiment comparison between engineering acid dew point and. Taking a 600mw boiler as an example, the acid dewpoint temperature of the flue gas flow is tested. Pdf knowledge of the sulfuric acid dewpoint temperature adt is important in many combustion processes. The acid dewpoint also acid dew point of a flue gas i.
Aug 25, 2017 acid dew point corrosion is very common in the oil industry. Evaluation of methods for measurement of s03h2s04 in flue gas. Saturation temperature of water at total pressure of exhaust flue gas c c. Check your flue gas sox acid dew point temperature. Dew point measurements for the wellstudied case of pure co2water agreed well with previous theoretical and experimental data over the range of pressure up to. Page dew point calculator protected without password modified raoults law, one term margules gert a x1x2 system acetone1methanol2, b 0.
The dew point is the temperature to which air must be cooled to become saturated with water vapor. Direct measurement, giving accurate and reliable monitoring of the sulphuric acid dewpoint temperature will assist with online control of flue gas temperatures. Atmospheric dew point is what that dew point would be if the air were expanded to atm pressure or 0 psig. So2so3 dewpoint petroleum refining engineering engtips. Then, the measured acid dew point is compared with the acid dew point obtained by using the existing empirical formula.
Air preheat solutions, steam reformer expansion, monitor combustion, low nox burner modification and air heater modification. Calculation and analysis of acid dewpoint temperature. All values are dependent on boundary conditions like the conversion rate from so. Dew point calculation you can physically determine the dew point temperature with a device called a hygrometer. Pdf acid dewpoint temperature measurement and its use in. The amount of contaminants in the fuel is directly correlated with the concentration of the acid droplets, and therefore with the degree of corrosion. You can use this dew point calculator to determine the dew point temperature t dew according to the temperature of the air t and the relative humidity rh you can calculate the dew point in three simple steps. The dew point temperature for the water can be calculated using the equation 4. Sulfuric acid and hydrochloric acid dewpoint corrosion fig. For example, a combustion product gas, with 10 volume percentage of water vapor and containing no acid gases, has a water vapor dew point of about 45. Pressure dew point vs atmospheric dew point pressure dew point is the dew point at the actual pressure. The temperature of flue gas should be controlled to be higher than the acid dew point to avoid fouling and corrosion of heating surfaces in the second pass of boilers. Flue gas dew point temperatures engineering toolbox. If a fuel with sulfur is burned under similar conditions along with water dew point, acid dew point takes place at about 240f 116c.
Corrosion leak occurred due to severe hcl aciddewpoint corrosion just below wellhead on 2 after only 70 days of initial steam production duplex stainless 2507 alloy seamwelded casing selected 4,000 feet of 858 and 758 alloy casing alloy casing installed january 2017. The acid dewpoint is important to know because excessive acid condensation will lead to increased corrosion of process equipment. If you have any questions, please feel free to contact us. Application note 02 acid dewpoint temperature measurement. The acidity is formed by flue gases which are produced in the refinery. These have not been added as so2 and so3 are the major ones of interest. When the temperature reaches the dew point, the acid becomes liquid and attacks the surface of metallic materials. Temperature far below acid dew point, to asure a high level of h 2 so 4 condensation. As previously stated, the iridescent ring method should give higher dew point values than the droplet method. Dewpoint calculation 1 introduction the dewpoint temperature can easily be calculated from the relative humidity and temperature. The sulfur trioxide combines with moisture to form sulfuric acid h2so4 see. Sulfuric acid condenses at temperatures well above 100c 212f. Mar 08, 2016 accurate knowledge in predicting acid dew point is required.
Welcome to the dew point calculator use the sliders to explore combinations of temperature t, relative humidity rh, and dew point dp to compare the. Please note that water presence tends to flatten the condensation curve. As a practical matter, most samples of gases from combustion processes where coal or oil is the fuel, contain about 10%12% water. The flue gas composition of n2, ar, o2, co2, co, so2 and h2o can be input in either of weight% or volume%, and for enthalpy calculation the reference temperature should be input. If the gas temperature drops below the acid dewpoint, sulfuric acid aerosol is formed, and a film of sulfuric acid also will form on any exposed surface with a temperature below the dewpoint. Acid dew point corrosion is very common in the oil industry. T stands for the observed temperature in degrees celsius. Thus, based on previous research achievements, a measuring device is designed based on the principle of conductive dew point meter, and the acid dew points under different flue gas conditions are measured in this work. Reliability of dewpoint estimation depends not only on the equation but also on. The dew point calculator will inter convert between various units of measurement.
The acid dew point of a flue gas, at a given pressure, is often referred to as the point at which the flue gas is saturated with. There are many methods used world over to contain cold end corrosion. H2o in flue gas % vol lab analysis calculations for recommended flue gas temperature to avoid sdew point. When further cooled, the airborne water vapour will condense to form liquid water.
The dewpoint temperature t d of a sample of air with vapor pressure e is the temperature to which it must be cooled to become saturated, i. Accuracy of analysis, and thus hydrocarbon dew point calculation, is dependant on correct and regular use of specialist reference gases an indirect method of determining hydrocarbon dew point relying on the correct application and suitability of the equation of state being used susceptible to measurement errors due to limit of. Increase performance provides fired process solutions for petrochemical refineries. Acid dew point temperature for 5 typical acid gases acker. Estimation of combustion flue gas acid dew point during heat recovery and efficiency gain. The dewpoint temperature is the temperature to which the air must be cooled to reach saturation assuming air. Td stands for the dew point temperature in degrees celsius. The theory explains how fog formation in the gas reduces the rate of acid deposition with a certain band of temperature between the acid dew point and the water dew point. Dew point for flue gas of powerplant exhaust iapws. But the temperature must not be so low that sulfur from the fuel will condense as sulfuric acidgiving a very corrosive flue gas. Condensation curves are based on experience and empirical data.
A new correlation accurately predicts the fluegas sulfuric acid dewpoints to mitigate corrosion problems in process equipments and heatrecovery systems. Acid dew point temperature for 5 typical acid gases. In order to solve these problems,the formula of the acid dew point in the thermal calculation from the former u. Many workers developed and used methods for measuring acid dew points, but there was little agreement between them until p. Imperial units are used courtney dehn process manager tg engineering calgary canada. H2o in flue gas % vol lab analysis calculations for recommended flue gas temperature to avoid s dew point.
In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures more are normally over the acid dewpoint. Dew points of ammonium bisulfate, sodium bisulfate, sulfuric acid, water, etc. Evaluation of methods for measurement of s03h2s04 in flue. The dew point temperature is the temperature to which the air must be cooled to reach saturation assuming air pressure remains the same. When air cools to its dew point through contact with a surface that is colder than the. Prediction of acid dew point in flue gas of boilers. Site reading so2 in flue gas vol % results sdew point temperature deg. To calculate the dew point of a stream which takes into account the acid concentration, use the calculator below. But this formula still has some problems, such as the desulphurization ability of different fuels, classification of sulfur content in fuel and the factors of so2 transferred into so3.
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